| Beyond fossil fuel–driven nitrogen transformations JG Chen, RM Crooks, LC Seefeldt, KL Bren, RM Bullock, ... Science 360 (6391), eaar6611, 2018 | 1782 | 2018 |
| Carbon monoxide and cyanide ligands in a classical organometallic complex model for Fe‐only hydrogenase EJ Lyon, IP Georgakaki, JH Reibenspies, MY Darensbourg Angewandte Chemie International Edition 38 (21), 3178-3180, 1999 | 492 | 1999 |
| The Hydrophilic Phosphatriazaadamantane Ligand in the Development of H2 Production Electrocatalysts: Iron Hydrogenase Model Complexes R Mejia-Rodriguez, D Chong, JH Reibenspies, MP Soriaga, ... Journal of the American Chemical Society 126 (38), 12004-12014, 2004 | 477 | 2004 |
| Oxygen capture by sulfur in nickel thiolates CA Grapperhaus, MY Darensbourg Accounts of chemical research 31 (8), 451-459, 1998 | 375 | 1998 |
| The bio-organometallic chemistry of active site iron in hydrogenases MY Darensbourg, EJ Lyon, JJ Smee Coordination chemistry reviews 206, 533-561, 2000 | 359 | 2000 |
| Coordination sphere flexibility of active-site models for Fe-only hydrogenase: Studies in intra-and intermolecular diatomic ligand exchange EJ Lyon, IP Georgakaki, JH Reibenspies, MY Darensbourg Journal of the American Chemical Society 123 (14), 3268-3278, 2001 | 352 | 2001 |
| H/D Exchange Reactions in Dinuclear Iron Thiolates as Activity Assay Models of Fe−H2ase X Zhao, IP Georgakaki, ML Miller, JC Yarbrough, MY Darensbourg Journal of the American Chemical Society 123 (39), 9710-9711, 2001 | 336 | 2001 |
| The organometallic active site of [Fe] hydrogenase: models and entatic states MY Darensbourg, EJ Lyon, X Zhao, IP Georgakaki Proceedings of the National Academy of Sciences 100 (7), 3683-3688, 2003 | 329 | 2003 |
| A mixed-valent, Fe (II) Fe (I), diiron complex reproduces the unique rotated state of the [FeFe] hydrogenase active site T Liu, MY Darensbourg Journal of the American Chemical Society 129 (22), 7008-7009, 2007 | 327 | 2007 |
| Catalysis of H2/D2 Scrambling and Other H/D Exchange Processes by [Fe]-Hydrogenase Model Complexes X Zhao, IP Georgakaki, ML Miller, R Mejia-Rodriguez, CY Chiang, ... Inorganic chemistry 41 (15), 3917-3928, 2002 | 309 | 2002 |
| Fundamental properties of small molecule models of Fe-only hydrogenase: computations relative to the definition of an entatic state in the active site IP Georgakaki, LM Thomson, EJ Lyon, MB Hall, MY Darensbourg Coordination chemistry reviews 238, 255-266, 2003 | 203 | 2003 |
| Reactions of transition metal carbonyls with organolithium compounds. II. Prediction of nucleophilic attack at carbon and resultant stereochemistry DJ Darensbourg, MY Darensbourg Inorganic Chemistry 9 (7), 1691-1694, 1970 | 201 | 1970 |
| Experimental Organometallic Chemistry: A practicum in synthesis and characterization AL Wayda, MY Darensbourg American Chemical Society, 1987 | 195 | 1987 |
| De Novo design of synthetic di-iron (I) complexes as structural models of the reduced form of iron− iron hydrogenase JW Tye, MY Darensbourg, MB Hall Inorganic Chemistry 45 (4), 1552-1559, 2006 | 194 | 2006 |
| Electrocatalysis of hydrogen production by active site analogues of the iron hydrogenase enzyme: structure/function relationships D Chong, IP Georgakaki, R Mejia-Rodriguez, J Sanabria-Chinchilla, ... Dalton Transactions, 4158-4163, 2003 | 186 | 2003 |
| Study of Sulfinate and Sulfenate Complexes Derived from the Oxygenation of Thiolate Sulfur in [1, 5-Bis (2-mercapto-2-methylpropyl)-1, 5-diazacyclooctanato (2-)] nickel (II) RM Buonomo, I Font, MJ Maguire, JH Reibenspies, T Tuntulani, ... Journal of the American Chemical Society 117 (3), 963-973, 1995 | 179 | 1995 |
| Synthetic Support of De Novo Design: Sterically Bulky [FeFe]‐Hydrogenase Models ML Singleton, N Bhuvanesh, JH Reibenspies, MY Darensbourg Angewandte Chemie International Edition 47 (49), 9492-9495, 2008 | 174 | 2008 |
| Dual electron uptake by simultaneous iron and ligand reduction in an N-heterocyclic carbene substituted [FeFe] hydrogenase model compound JW Tye, J Lee, HW Wang, R Mejia-Rodriguez, JH Reibenspies, MB Hall, ... Inorganic chemistry 44 (16), 5550-5552, 2005 | 168 | 2005 |
| Ion pairing effects on transition metal carbonyl anions MY Darensbourg Progress in inorganic chemistry, 221-274, 1985 | 165 | 1985 |
| Thiolate Bridged Nickel–Iron Complexes Containing both Iron(0) and Iron(II) Carbonyls CH Lai, JH Reibenspies, MY Darensbourg Angewandte Chemie International Edition in English 35 (20), 2390-2393, 1996 | 163 | 1996 |