Stable cyclic (alkyl)(amino) carbenes as rigid or flexible, bulky, electron-rich ligands for transition-metal catalysts: a quaternary carbon atom makes the difference V Lavallo, Y Canac, C Präsang, B Donnadieu, G Bertrand Angewandte Chemie (International ed. in English) 44 (35), 5705, 2005 | 1228 | 2005 |
Facile splitting of hydrogen and ammonia by nucleophilic activation at a single carbon center GD Frey, V Lavallo, B Donnadieu, WW Schoeller, G Bertrand Science 316 (5823), 439-441, 2007 | 1005 | 2007 |
Synthesis and characterization of a neutral tricoordinate organoboron isoelectronic with amines R Kinjo, B Donnadieu, MA Celik, G Frenking, G Bertrand Science 333 (6042), 610-613, 2011 | 586 | 2011 |
Synthesis of an extremely bent acyclic allene (a “carbodicarbene”): a strong donor ligand CA Dyker, V Lavallo, B Donnadieu, G Bertrand Angewandte Chemie International Edition 47 (17), 3206-3209, 2008 | 523 | 2008 |
Crystalline 1H-1, 2, 3-triazol-5-ylidenes: new stable mesoionic carbenes (MICs) G Guisado-Barrios, J Bouffard, B Donnadieu, G Bertrand Angewandte Chemie (International ed. in English) 49 (28), 4759, 2010 | 480 | 2010 |
Isolation of a C5-deprotonated imidazolium, a crystalline “abnormal” N-heterocyclic carbene E Aldeco-Perez, AJ Rosenthal, B Donnadieu, P Parameswaran, ... Science 326 (5952), 556-559, 2009 | 475 | 2009 |
Homogeneous catalytic hydroamination of alkynes and allenes with ammonia V Lavallo, GD Frey, B Donnadieu, M Soleilhavoup, G Bertrand Angewandte Chemie (International ed. in English) 47 (28), 5224, 2008 | 442 | 2008 |
CO fixation to stable acyclic and cyclic alkyl amino carbenes: stable amino ketenes with a small HOMO–LUMO gap V Lavallo, Y Canac, B Donnadieu, WW Schoeller, G Bertrand Angewandte Chemie (International ed. in English) 45 (21), 3488, 2006 | 353 | 2006 |
A rigid cyclic (alkyl)(amino) carbene ligand leads to isolation of low-coordinate transition-metal complexes V Lavallo, Y Canac, A DeHope, B Donnadieu, G Bertrand Angewandte Chemie (International ed. in English) 44 (44), 7236, 2005 | 346 | 2005 |
Nonmetal-mediated fragmentation of P4: isolation of P1 and P2 bis (carbene) adducts O Back, G Kuchenbeiser, B Donnadieu, G Bertrand Angew. Chem., Int. Ed 48 (30), 5530-5533, 2009 | 340 | 2009 |
Allene formation by gold catalyzed cross-coupling of masked carbenes and vinylidenes V Lavallo, GD Frey, S Kousar, B Donnadieu, G Bertrand Proceedings of the National Academy of Sciences 104 (34), 13569-13573, 2007 | 339 | 2007 |
Carbene Activation of P4 and Subsequent Derivatization JD Masuda, WW Schoeller, B Donnadieu, G Bertrand Angewandte Chemie International Edition 46 (37), 7052-7055, 2007 | 314 | 2007 |
Cyclopropenylidenes: From interstellar space to an isolated derivative in the laboratory V Lavallo, Y Canac, B Donnadieu, WW Schoeller, G Bertrand Science 312 (5774), 722-724, 2006 | 301 | 2006 |
Aryl CH Activation by CuII To Form an Organometallic Aryl–CuIII Species: A Novel Twist on Copper Disproportionation X Ribas, DA Jackson, B Donnadieu, J Mahía, T Parella, R Xifra, ... Angewandte Chemie International Edition 41 (16), 2991-2994, 2002 | 299 | 2002 |
Intramolecular “hydroiminiumation” of alkenes: application to the synthesis of conjugate acids of cyclic alkyl amino carbenes (CAACs) R Jazzar, RD Dewhurst, JB Bourg, B Donnadieu, Y Canac, G Bertrand Angewandte Chemie (International ed. in English) 46 (16), 2899, 2007 | 298 | 2007 |
Isolation of crystalline carbene-stabilized P2-radical cations and P2-dications O Back, B Donnadieu, P Parameswaran, G Frenking, G Bertrand Nature Chemistry 2 (5), 369-373, 2010 | 293 | 2010 |
Oligonuclear 3d–4f Complexes as Tectons in Designing Supramolecular Solid‐State Architectures: Impact of the Nature of Linkers on the Structural Diversity R Gheorghe, P Cucos, M Andruh, JP Costes, B Donnadieu, S Shova Chemistry–A European Journal 12 (1), 187-203, 2006 | 291 | 2006 |
NHC-Mediated Aggregation of P4: Isolation of a P12 Cluster JD Masuda, WW Schoeller, B Donnadieu, G Bertrand Journal of the American Chemical Society 129 (46), 14180-14181, 2007 | 276 | 2007 |
Activation of SiÀH, BÀH, and PÀH Bonds at a Single Nonmetal Center GD Frey, JD Masuda, B Donnadieu, G Bertrand Angew. Chem. Int. Ed 49, 9444-9447, 2010 | 259 | 2010 |
Synthesis of a simplified version of stable bulky and rigid cyclic (alkyl)(amino) carbenes, and catalytic activity of the ensuing gold (I) complex in the three-component … X Zeng, GD Frey, R Kinjo, B Donnadieu, G Bertrand Journal of the American Chemical Society 131 (24), 8690-8696, 2009 | 256 | 2009 |