| Recent advances in the Pauson–Khand reaction and related [2+ 2+ 1] cycloadditions KM Brummond, JL Kent Tetrahedron 56 (21), 3263-3283, 2000 | 660 | 2000 |
| Covalent modifiers: A chemical perspective on the reactivity of α, β-unsaturated carbonyls with thiols via hetero-Michael addition reactions PA Jackson, JC Widen, DA Harki, KM Brummond Journal of medicinal chemistry 60 (3), 839-885, 2017 | 493 | 2017 |
| Synthesizing allenes today (1982-2006) KM Brummond, JE DeForrest Synthesis 2007 (06), 795-818, 2007 | 256 | 2007 |
| A Rhodium (I)-catalyzed formal allenic Alder Ene reaction for the rapid and stereoselective assembly of cross-conjugated trienes KM Brummond, H Chen, P Sill, L You Journal of the American Chemical Society 124 (51), 15186-15187, 2002 | 193 | 2002 |
| An allenic Pauson− Khand-type reaction: A reversal in π-bond selectivity and the formation of seven-membered rings KM Brummond, H Chen, KD Fisher, AD Kerekes, B Rickards, PC Sill, ... Organic Letters 4 (11), 1931-1934, 2002 | 167 | 2002 |
| A new allenic Pauson-Khand cycloaddition for the preparation of α-methylene cyclopentenones JL Kent, H Wan, KM Brummond Tetrahedron letters 36 (14), 2407-2410, 1995 | 143 | 1995 |
| Synthesis and Photophysical Properties of a Series of Cyclopenta[b]naphthalene Solvatochromic Fluorophores E Benedetti, LS Kocsis, KM Brummond Journal of the American Chemical Society 134 (30), 12418-12421, 2012 | 141 | 2012 |
| Microwave-assisted intramolecular [2+ 2] allenic cycloaddition reaction for the rapid assembly of bicyclo [4.2. 0] octa-1, 6-dienes and bicyclo [5.2. 0] nona-1, 7-dienes KM Brummond, D Chen Organic Letters 7 (16), 3473-3475, 2005 | 121 | 2005 |
| An intramolecular allenic [2+ 2+ 1] cycloaddition KM Brummond, H Wan, JL Kent The Journal of Organic Chemistry 63 (19), 6535-6545, 1998 | 112 | 1998 |
| Allenes and transition metals: a diverging approach to heterocycles KM Brummond, B Mitasev Organic Letters 6 (13), 2245-2248, 2004 | 108 | 2004 |
| A Short Synthesis of the Potent Antitumor Agent ( )-Hydroxymethylacylfulvene Using an Allenic Pauson-Khand Type Cycloaddition KM Brummond, J Lu Journal of the American Chemical Society 121 (21), 5087-5088, 1999 | 106 | 1999 |
| Unique Strategy for the Assembly of the Carbon Skeleton of Guanacastepene A Using an Allenic Pauson− Khand-Type Reaction KM Brummond, D Gao Organic Letters 5 (19), 3491-3494, 2003 | 100 | 2003 |
| Chiral Nonracemic α-Alkylidene and α-Silylidene Cyclopentenones from Chiral Allenes Using an Intramolecular Allenic Pauson− Khand-Type Cycloaddition KM Brummond, AD Kerekes, H Wan The Journal of Organic Chemistry 67 (15), 5156-5163, 2002 | 98 | 2002 |
| Differentiating mechanistic possibilities for the thermal, intramolecular [2+ 2] cycloaddition of Allene− Ynes MR Siebert, JM Osbourn, KM Brummond, DJ Tantillo Journal of the American Chemical Society 132 (34), 11952-11966, 2010 | 89 | 2010 |
| A Thermal Dehydrogenative Diels–Alder Reaction of Styrenes for the Concise Synthesis of Functionalized Naphthalenes LS Kocsis, E Benedetti, KM Brummond Organic letters 14 (17), 4430-4433, 2012 | 86 | 2012 |
| A rapid synthesis of hydroxymethylacylfulvene (HMAF) using the allenic Pauson− Khand reaction. A synthetic approach to either enantiomer of this illudane structure KM Brummond, J Lu, J Petersen Journal of the American Chemical Society 122 (20), 4915-4920, 2000 | 81 | 2000 |
| A formal total synthesis of (−)-FR901483, using a tandem cationic aza-Cope rearrangement/Mannich cyclization approach KM Brummond, S Hong The Journal of Organic Chemistry 70 (3), 907-916, 2005 | 80 | 2005 |
| α-Chlorination of ketones using p-toluenesulfonyl chloride KM Brummond, KD Gesenberg Tetrahedron letters 40 (12), 2231-2234, 1999 | 77 | 1999 |
| The allenic Pauson-Khand cycloaddition. Dependence in π-bond selectivity on substrate structure KM Brummond, H Wan Tetrahedron letters 39 (9), 931-934, 1998 | 77 | 1998 |
| Rhodium (I)-catalyzed ene-allene carbocyclization strategy for the formation of azepines and oxepines KM Brummond, H Chen, B Mitasev, AD Casarez Organic Letters 6 (13), 2161-2163, 2004 | 76 | 2004 |
Daniel A. HarkiNorthrop Professor, Department of Medicinal Chemistry, University of MinnesotaDirección de correo verificada de umn.edu
